Please use this identifier to cite or link to this item: https://scholarhub.balamand.edu.lb/handle/uob/4996
Title: FeIII48 -Containing 96-Tungsto-16-Phosphate: Synthesis, Structure, Magnetism and Electrochemistry
Authors: Goura, Joydeb
Bassil, Bassem 
Bindra, Jasleen K
Rutkowska, Iwona A
Kulesza, Pawel J
Dalal, Naresh S
Kortz, Ulrich
Keywords: Electrochemistry
Iron
Macrocycle
Magnetism
Polyoxometalates
Issue Date: 2020-12-04
Part of: Chemistry - A European Journal
Volume: 26
Issue: 68
Start page: 15821
End page: 15824
Abstract: 
The 48-FeIII -containing 96-tungsto-16-phosphate, [FeIII48 (OH)76 (H2 O)16 (HP2 W12 O48 )8 ]36- (Fe48 ), has been synthesized and structurally characterized. This polyanion comprises eight equivalent {FeIII6 P2 W12 } units that are linked in an end-on fashion forming a macrocyclic assembly that contains more iron centers than any other polyoxometalate (POM) known to date. The novel Fe48 was synthesized by a simple one-pot reaction of an {Fe22 } coordination complex with the hexalacunary {P2 W12 } POM precursor in water. The title polyanion was characterized by single-crystal XRD, FTIR, TGA, magnetic and electrochemical studies.
URI: https://scholarhub.balamand.edu.lb/handle/uob/4996
ISSN: 09476539
DOI: 10.1002/chem.202002832
Ezproxy URL: Link to full text
Type: Journal Article
Appears in Collections:Department of Chemistry

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