UOBScholar Hub
UOB Libraries created the UOBScholar Hub, an Institutional Repository (IR) for archiving and collecting all the research output of the UOB community. It aims to improve the visibility, usage and impact of research conducted at UOB. Materials included are: academic journal articles, conference papers and presentations, books and book chapters, ongoing research papers, reports and patents.
Submit your Publication
Please use this identifier to cite or link to this item:
https://scholarhub.balamand.edu.lb/handle/uob/4996| Title: | FeIII48 -containing 96-tungsto-16-phosphate: synthesis, structure, magnetism and electrochemistry | Authors: | Goura, Joydeb Bassil, Bassem Bindra, Jasleen K Rutkowska, Iwona A Kulesza, Pawel J Dalal, Naresh S Kortz, Ulrich |
Affiliations: | Faculty of Arts and Sciences | Keywords: | Electrochemistry Iron Macrocycle Magnetism Polyoxometalates |
Issue Date: | 2020 | Part of: | Chemistry - A European Journal | Volume: | 26 | Issue: | 68 | Start page: | 15821 | End page: | 15824 | Abstract: | The 48-FeIII -containing 96-tungsto-16-phosphate, [FeIII48 (OH)76 (H2 O)16 (HP2 W12 O48 )8 ]36- (Fe48 ), has been synthesized and structurally characterized. This polyanion comprises eight equivalent {FeIII6 P2 W12 } units that are linked in an end-on fashion forming a macrocyclic assembly that contains more iron centers than any other polyoxometalate (POM) known to date. The novel Fe48 was synthesized by a simple one-pot reaction of an {Fe22 } coordination complex with the hexalacunary {P2 W12 } POM precursor in water. The title polyanion was characterized by single-crystal XRD, FTIR, TGA, magnetic and electrochemical studies. |
URI: | https://scholarhub.balamand.edu.lb/handle/uob/4996 | ISSN: | 09476539 | DOI: | 10.1002/chem.202002832 | Ezproxy URL: | Link to full text | Type: | Journal Article |
| Appears in Collections: | Department of Chemistry |
Show full item record
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.