Please use this identifier to cite or link to this item: https://scholarhub.balamand.edu.lb/handle/uob/4996
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dc.contributor.authorGoura, Joydeben_US
dc.contributor.authorBassil, Bassemen_US
dc.contributor.authorBindra, Jasleen Ken_US
dc.contributor.authorRutkowska, Iwona Aen_US
dc.contributor.authorKulesza, Pawel Jen_US
dc.contributor.authorDalal, Naresh Sen_US
dc.contributor.authorKortz, Ulrichen_US
dc.date.accessioned2021-03-24T09:56:51Z-
dc.date.available2021-03-24T09:56:51Z-
dc.date.issued2020-12-04-
dc.identifier.issn09476539-
dc.identifier.urihttps://scholarhub.balamand.edu.lb/handle/uob/4996-
dc.description.abstractThe 48-FeIII -containing 96-tungsto-16-phosphate, [FeIII48 (OH)76 (H2 O)16 (HP2 W12 O48 )8 ]36- (Fe48 ), has been synthesized and structurally characterized. This polyanion comprises eight equivalent {FeIII6 P2 W12 } units that are linked in an end-on fashion forming a macrocyclic assembly that contains more iron centers than any other polyoxometalate (POM) known to date. The novel Fe48 was synthesized by a simple one-pot reaction of an {Fe22 } coordination complex with the hexalacunary {P2 W12 } POM precursor in water. The title polyanion was characterized by single-crystal XRD, FTIR, TGA, magnetic and electrochemical studies.en_US
dc.language.isoengen_US
dc.subjectElectrochemistryen_US
dc.subjectIronen_US
dc.subjectMacrocycleen_US
dc.subjectMagnetismen_US
dc.subjectPolyoxometalatesen_US
dc.titleFeIII48 -Containing 96-Tungsto-16-Phosphate: Synthesis, Structure, Magnetism and Electrochemistryen_US
dc.typeJournal Articleen_US
dc.identifier.doi10.1002/chem.202002832-
dc.identifier.pmid32744748-
dc.identifier.scopus2-s2.0-85096641165-
dc.identifier.urlhttps://api.elsevier.com/content/abstract/scopus_id/85096641165-
dc.description.volume26en_US
dc.description.issue68en_US
dc.description.startpage15821en_US
dc.description.endpage15824en_US
dc.date.catalogued2021-03-24-
dc.description.statusPublisheden_US
dc.identifier.ezproxyURLhttp://ezsecureaccess.balamand.edu.lb/login?url=https://doi.org/10.1002/chem.202002832en_US
dc.relation.ispartoftextChemistry - A European Journalen_US
Appears in Collections:Department of Chemistry
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