Please use this identifier to cite or link to this item:
https://scholarhub.balamand.edu.lb/handle/uob/4996
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Goura, Joydeb | en_US |
dc.contributor.author | Bassil, Bassem | en_US |
dc.contributor.author | Bindra, Jasleen K | en_US |
dc.contributor.author | Rutkowska, Iwona A | en_US |
dc.contributor.author | Kulesza, Pawel J | en_US |
dc.contributor.author | Dalal, Naresh S | en_US |
dc.contributor.author | Kortz, Ulrich | en_US |
dc.date.accessioned | 2021-03-24T09:56:51Z | - |
dc.date.available | 2021-03-24T09:56:51Z | - |
dc.date.issued | 2020 | - |
dc.identifier.issn | 09476539 | - |
dc.identifier.uri | https://scholarhub.balamand.edu.lb/handle/uob/4996 | - |
dc.description.abstract | The 48-FeIII -containing 96-tungsto-16-phosphate, [FeIII48 (OH)76 (H2 O)16 (HP2 W12 O48 )8 ]36- (Fe48 ), has been synthesized and structurally characterized. This polyanion comprises eight equivalent {FeIII6 P2 W12 } units that are linked in an end-on fashion forming a macrocyclic assembly that contains more iron centers than any other polyoxometalate (POM) known to date. The novel Fe48 was synthesized by a simple one-pot reaction of an {Fe22 } coordination complex with the hexalacunary {P2 W12 } POM precursor in water. The title polyanion was characterized by single-crystal XRD, FTIR, TGA, magnetic and electrochemical studies. | en_US |
dc.language.iso | eng | en_US |
dc.subject | Electrochemistry | en_US |
dc.subject | Iron | en_US |
dc.subject | Macrocycle | en_US |
dc.subject | Magnetism | en_US |
dc.subject | Polyoxometalates | en_US |
dc.title | FeIII48 -containing 96-tungsto-16-phosphate: synthesis, structure, magnetism and electrochemistry | en_US |
dc.type | Journal Article | en_US |
dc.identifier.doi | 10.1002/chem.202002832 | - |
dc.identifier.pmid | 32744748 | - |
dc.identifier.scopus | 2-s2.0-85096641165 | - |
dc.identifier.url | https://api.elsevier.com/content/abstract/scopus_id/85096641165 | - |
dc.contributor.affiliation | Faculty of Arts and Sciences | en_US |
dc.description.volume | 26 | en_US |
dc.description.issue | 68 | en_US |
dc.description.startpage | 15821 | en_US |
dc.description.endpage | 15824 | en_US |
dc.date.catalogued | 2021-03-24 | - |
dc.description.status | Published | en_US |
dc.identifier.ezproxyURL | http://ezsecureaccess.balamand.edu.lb/login?url=https://doi.org/10.1002/chem.202002832 | en_US |
dc.relation.ispartoftext | Chemistry - A European Journal | en_US |
dc.description.campus | FOM main campus | en_US |
Appears in Collections: | Department of Chemistry |
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