Please use this identifier to cite or link to this item: https://scholarhub.balamand.edu.lb/handle/uob/5386
Title: Transesterification of Refined Sunflower Oil to Biodiesel Using a CaO/ZSM-5 Powder Catalyst
Authors: Dahdah, Eliane
Estephane, Jane 
Moussa Chalouhi, Lena
Sammoury, Safa
El Khoury, Bilal
Gennequin, Cedric
Abi-Aad, Edmond
Aouad, Samer 
Affiliations: Department of Chemical Engineering 
Department of Chemistry 
Keywords: Biodiesel
Calcium oxide
Transesterification
Vegetable oils
ZSM-5 catalyst
Issue Date: 2022
Part of: Chemical engineering & technology
Volume: 45
Issue: 1
Start page: 51
End page: 57
Abstract: 
The production of biodiesel from refined sunflower vegetable oil over basic CaO/ZSM-5 catalysts was investigated. Several catalysts with various loadings of CaO on ZSM-5 were prepared, calcined at 800 °C, and characterized by N2 adsorption-desorption, X-ray diffraction, Fourier transform infrared spectroscopy, and CO2-temperature-programmed desorption techniques. Calcined catalysts were tested in the transesterification reaction and reaction conditions were optimized by varying the catalyst-to-oil ratio and reaction time. The most active catalyst was the CaO/ZSM-5 catalyst with a 35 wt % loading which gave the highest fatty acid methyl ester yield. The high catalytic activity was attributed to the active basic sites generated following CaO addition. Furthermore, the catalyst demonstrated stability against the leaching process.
URI: https://scholarhub.balamand.edu.lb/handle/uob/5386
ISSN: 09307516
DOI: 10.1002/ceat.202100174
Ezproxy URL: Link to full text
Type: Journal Article
Appears in Collections:Department of Chemistry
Department of Chemical Engineering

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