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https://scholarhub.balamand.edu.lb/handle/uob/2645| Title: | Ti2-containing 18-tungsto-2-arsenate(III) monolacunary host and the incorporation of a phenylantimony(III) guest. | Authors: | Wang , K.Y Lin, Zhengguo Bassil, Bassem Xing, X Haider, Ali Keita, Bineta Zhang, Guangjin Silvestru, C Kortz, Ulrich |
Affiliations: | Department of Chemistry | Issue Date: | 2015 | Part of: | Journal of Inorganic Chemistry | Volume: | 54 | Issue: | 22 | Start page: | 10530 | End page: | 10532 | Abstract: | The novel Ti2-containing, sandwich-type 18-tungsto-2-arsenate(III) [(Ti(IV)O)2(α-As(III)W9O33)2](14-) (1) was successfully synthesized by the reaction of [TiO](2+) species with [α-As(III)W9O33](9-). The monolacunary polyanion 1 is solution-stable, and a further reaction with 1 equiv of phenylantimony(III) dichloride resulted in [C6H5Sb(III)(Ti(IV)O)2(α-As(III)W9O33)2](12-) (2). Both polyanions 1 and 2 were structurally characterized in the solid state and solution. Electrochemical studies were also performed on both polyanions. |
URI: | https://scholarhub.balamand.edu.lb/handle/uob/2645 | Open URL: | Link to full text | Type: | Journal Article |
| Appears in Collections: | Department of Chemistry |
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