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|Title:||Ti2-Containing 18-Tungsto-2-Arsenate(III) Monolacunary Host and the Incorporation of a Phenylantimony(III) Guest.||Authors:||Wang , K.Y
|Affiliations:||Department of Chemistry||Issue Date:||2015||Part of:||Journal of Inorganic Chemistry||Volume:||54||Issue:||22||Start page:||10530||End page:||10532||Abstract:||
The novel Ti2-containing, sandwich-type 18-tungsto-2-arsenate(III) [(Ti(IV)O)2(α-As(III)W9O33)2](14-) (1) was successfully synthesized by the reaction of [TiO](2+) species with [α-As(III)W9O33](9-). The monolacunary polyanion 1 is solution-stable, and a further reaction with 1 equiv of phenylantimony(III) dichloride resulted in [C6H5Sb(III)(Ti(IV)O)2(α-As(III)W9O33)2](12-) (2). Both polyanions 1 and 2 were structurally characterized in the solid state and solution. Electrochemical studies were also performed on both polyanions.
|URI:||https://scholarhub.balamand.edu.lb/handle/uob/2645||Open URL:||Link to full text||Type:||Journal Article|
|Appears in Collections:||Department of Chemistry|
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