Please use this identifier to cite or link to this item: https://scholarhub.balamand.edu.lb/handle/uob/2645
Title: Ti2-containing 18-tungsto-2-arsenate(III) monolacunary host and the incorporation of a phenylantimony(III) guest.
Authors: Wang , K.Y
Lin, Zhengguo
Bassil, Bassem 
Xing, X
Haider, Ali
Keita, Bineta
Zhang, Guangjin
Silvestru, C
Kortz, Ulrich
Affiliations: Department of Chemistry 
Issue Date: 2015
Part of: Journal of Inorganic Chemistry
Volume: 54
Issue: 22
Start page: 10530
End page: 10532
Abstract: 
The novel Ti2-containing, sandwich-type 18-tungsto-2-arsenate(III) [(Ti(IV)O)2(α-As(III)W9O33)2](14-) (1) was successfully synthesized by the reaction of [TiO](2+) species with [α-As(III)W9O33](9-). The monolacunary polyanion 1 is solution-stable, and a further reaction with 1 equiv of phenylantimony(III) dichloride resulted in [C6H5Sb(III)(Ti(IV)O)2(α-As(III)W9O33)2](12-) (2). Both polyanions 1 and 2 were structurally characterized in the solid state and solution. Electrochemical studies were also performed on both polyanions.
URI: https://scholarhub.balamand.edu.lb/handle/uob/2645
Open URL: Link to full text
Type: Journal Article
Appears in Collections:Department of Chemistry

Show full item record

Record view(s)

15
checked on Dec 2, 2022

Google ScholarTM

Check


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.