Please use this identifier to cite or link to this item: https://scholarhub.balamand.edu.lb/handle/uob/2620
Title: Synthesis and structure of hexatungstochromate(III), [H3CrIIIW6O24]6-
Authors: Liu, Wenging
Lin, Zhengguo
Bassil, Bassem 
Oweini, Rami Al
Kortz, Ulrich
Affiliations: Department of Chemistry 
Keywords: Anderson-Evans structure
Chromium
Polyoxometalates
XRD
Issue Date: 2015
Part of: Chimia international journal of chemistry
Volume: 69
Issue: 9
Start page: 537
End page: 540
Abstract: 
The hexatungstochromate(III) [H3CrIIIW6O24]6- (1) was synthesized in aqueous, basic medium by simple reaction of chromium(III) nitrate nonahydrate and sodium tungstate dihydrate in a 1:6 ratio. Polyanion 1 represents the first Anderson-Evans type heteropolytungstate with a trivalent hetero element. The sodium salt of 1 with the formula Na6[H3CrIIIW6O24]·22H2O (1a) was fully characterized in the solid state by single crystal XRD, FT-IR spectroscopy, and thermogravimetric analysis.
URI: https://scholarhub.balamand.edu.lb/handle/uob/2620
Ezproxy URL: Link to full text
Type: Journal Article
Appears in Collections:Department of Chemistry

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