Please use this identifier to cite or link to this item: https://scholarhub.balamand.edu.lb/handle/uob/2617
Title: Synthesis and Characterization of 8-Yttrium(III)-Containing81-Tungsto-8-Arsenate(III), [Y8(CH3COO)(H2O)18(As2W19O68)4(W2O6)2(WO4)]43−
Authors: Ibrahim, Masooma
Kortz, Ulrich
Bassil, Bassem 
Affiliations: Department of Chemistry 
Keywords: Yttrium
Polyoxometalates
Tungsten
Structure
High-nuclearity
Issue Date: 2015
Part of: Journal of inorganics
Volume: 3
Issue: 2
Start page: 267
End page: 278
Abstract: 
The 8-yttrium(III)-containing 81-tungsto-8-arsenate(III) [Y8(CH3COO)(H2O)18(As2W19O68)4(W2O6)2(WO4)]43− (1) has been synthesized in a one-pot reaction of yttrium(III) ions with [B-α-AsW9O33]9− in 1 M NaOAc/HOAc buffer at pH 4.8. Polyanion 1 is composed of four {As2W19O68} units, two {W2O10} fragments, one {WO6} group, and eight YIII ions. The hydrated cesium-sodium salt of 1 (CsNa-1) was characterized in the solid-state by single-crystal XRD, FT-IR spectroscopy, thermogravimetric and elemental analyses.
URI: https://scholarhub.balamand.edu.lb/handle/uob/2617
Open URL: Link to full text
Type: Journal Article
Appears in Collections:Department of Chemistry

Show full item record

Record view(s)

1
checked on Aug 14, 2021

Google ScholarTM

Check


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.