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Title: | EPR simulation to confirm the formation of Ag6O5 complex on the surface of 10% Ag/CeO2 catalyst after the propylene oxidation reaction | Authors: | Hany, Sara Skaf, Mira Aouad, Samer Gennequin, Cédric Labaki, Madona Abi Aad, Edmond AbouKais, Antoine |
Affiliations: | Department of Chemistry | Keywords: | Ag2+ EPR Simulation Dimer Trimer Propylene |
Issue Date: | 2018 | Part of: | Journal of chemical physics letters | Volume: | 703 | Start page: | 94 | End page: | 96 | Abstract: | Ag2+(b) species were detected by electron paramagnetic resonance (EPR) on silver loaded over ceria by impregnation in a previous work. Contrasting the EPR simulation with the experimental measurements evidenced that, upon propene oxidation, the Ag2+(b) species transform into two clusters each containing 2 Ag2+ and 1 Ag+ species. This cluster is composed of two parallel electron spins (dimer) and three nuclear spins (trimer). Such a result led us to suggest that initially, Ag2+(b) species clusters were formed by three parallel electron spins. The ferromagnetic character of Ag2+(b) species may explain their catalytic performance towards total oxidation of propylene. |
URI: | https://scholarhub.balamand.edu.lb/handle/uob/1962 | DOI: | 10.1016/j.cplett.2018.05.019 | Ezproxy URL: | Link to full text | Type: | Journal Article |
Appears in Collections: | Department of Chemistry |
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