Please use this identifier to cite or link to this item:
https://scholarhub.balamand.edu.lb/handle/uob/1718
Title: | Cation effect on formation of preyssler-type 30-tungsto-5-phosphate: enhanced Yield of Na-encapsulated derivative and direct synthesis of Ca- and Bi-encapsulated derivatives | Authors: | Hayashi, A Haioka , T Takahashi, K Bassil, Bassem Kortz, Ulrich Sano , T Sadakane, M.Z |
Affiliations: | Department of Chemistry | Issue Date: | 2015 | Part of: | journal of anorganische und allgemeine Chemie | Volume: | 641 | Issue: | 15 | Start page: | 2670 | End page: | 2676 | Abstract: | The effect of cations in a reaction mixture for the preparation of the Preyssler-Jeannin-Pope type 30-tungsto-5-phosphate [P5W30O110Na]14– is investigated. Reaction of phosphate and tungstate with a P/W ratio of ca. 3.9 in an acidic aqueous solution without cations selectively leads to the Dawson-type 18-tungsto-2-phosphate, [P2W18O62]6–. Amongst all the alkali cations, only Na+ allows formation of the Preyssler-type polyanion [P5W30O110Na]14–, with an encapsulated Na+ ion, and the product yield can be improved by increasing Na+ amount. The presence of Li+ ions instead results in the Dawson-type polyanion [P2W18O62]6–, whereas K+, Rb+, and Cs+ selectively result in the Keggin-type polyanion [PW12O40]3–. An improved synthetic procedure for the Na+-encapsulated Preyssler-ion leading to a higher isolated yield is presented. Furthermore, addition of Ca2+ and Bi3+ compounds allows formation of the Ca2+- and Bi3+-encapsulated Preyssler-type polyanions, [P5W30O110Ca]13– and [P5W30O110Bi]12–, respectively. Furthermore, single-crystal XRD structure of the Bi3+-encapsulated Preyssler-type polyanions, [P5W30O110Bi]12–, is presented for the first time. |
URI: | https://scholarhub.balamand.edu.lb/handle/uob/1718 | DOI: | 10.1002/zaac.201500679 | Ezproxy URL: | Link to full text | Type: | Journal Article |
Appears in Collections: | Department of Chemistry |
Show full item record
SCOPUSTM
Citations
19
checked on Nov 9, 2024
Record view(s)
81
checked on Nov 14, 2024
Google ScholarTM
Check
Altmetric
Altmetric
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.