Please use this identifier to cite or link to this item: https://scholarhub.balamand.edu.lb/handle/uob/5001
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dc.contributor.authorGoura, Joydeben_US
dc.contributor.authorSundar, Anusreeen_US
dc.contributor.authorBassil, Bassemen_US
dc.contributor.authorĆirić-Marjanović, Gordanaen_US
dc.contributor.authorBajuk-Bogdanović, Danicaen_US
dc.contributor.authorKortz, Ulrichen_US
dc.date.accessioned2021-03-29T08:31:40Z-
dc.date.available2021-03-29T08:31:40Z-
dc.date.issued2020-
dc.identifier.issn00201669-
dc.identifier.urihttps://scholarhub.balamand.edu.lb/handle/uob/5001-
dc.description.abstractWe report on the first example of a peroxouranium-containing {P8W48} wheel, [{(UO2)4(O2)4}2(P8W48O184)]40- (1), which was synthesized by a one-pot reaction of UO2(NO3)2·6H2O with the 48-tungsto-8-phosphate wheel [H7P8W48O184]33- and aqueous hydrogen peroxide in a pH 6 lithium acetate solution at 50 °C. Polyanion 1 comprises two tetrauranyl squares with side-on peroxo bridging ligands in the cavity of the {P8W48} wheel, and was isolated as the hydrated potassium-lithium salt K18Li22[{(UO2)4(O2)4}2(P8W48O184)]·133H2O (KLi-1), which was characterized in the solid state by single-crystal X-ray diffraction, as well as thermogravimetric and elemental analyses. A detailed Fourier transform infrared and Raman spectroscopy study was also performed.en_US
dc.language.isoengen_US
dc.publisherACSen_US
dc.titlePeroxouranyl-containing W48 wheel: synthesis, structure, and detailed infrared and raman spectroscopy studyen_US
dc.typeJournal Articleen_US
dc.identifier.doi10.1021/acs.inorgchem.0c02858-
dc.identifier.pmid33215914-
dc.identifier.scopus2-s2.0-85097584294-
dc.identifier.urlhttps://api.elsevier.com/content/abstract/scopus_id/85097584294-
dc.contributor.affiliationFaculty of Arts and Sciencesen_US
dc.description.volume59en_US
dc.description.issue23en_US
dc.description.startpage16789en_US
dc.description.endpage16794en_US
dc.description.statusPublisheden_US
dc.identifier.openURLhttps://pubs.acs.org/doi/10.1021/acs.inorgchem.0c02858en_US
dc.relation.ispartoftextInorganic Chemistryen_US
dc.description.campusFOM main campusen_US
crisitem.author.parentorgFaculty of Arts and Sciences-
Appears in Collections:Department of Chemistry
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