Please use this identifier to cite or link to this item:
https://scholarhub.balamand.edu.lb/handle/uob/2252
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Haider, Ali | en_US |
dc.contributor.author | Ibrahim, Masooma | en_US |
dc.contributor.author | Bassil, Bassem | en_US |
dc.contributor.author | Carey, Akina M. | en_US |
dc.contributor.author | Nguyen Viet, A | en_US |
dc.contributor.author | Xing, X | en_US |
dc.contributor.author | Ayass, Wassim W. | en_US |
dc.contributor.author | Minambres, J.F | en_US |
dc.contributor.author | Liu, R. | en_US |
dc.contributor.author | Zhang, Guangjin | en_US |
dc.contributor.author | Keita, Bineta | en_US |
dc.contributor.author | Mereacre, V | en_US |
dc.contributor.author | Powell, A.K | en_US |
dc.contributor.author | Balinski, K | en_US |
dc.contributor.author | N'Diaye, A.T | en_US |
dc.contributor.author | Kuepper, K | en_US |
dc.contributor.author | Chen, H.Y | en_US |
dc.contributor.author | Stimming, U | en_US |
dc.contributor.author | Kortz, Ulrich | en_US |
dc.date.accessioned | 2020-12-23T09:09:32Z | - |
dc.date.available | 2020-12-23T09:09:32Z | - |
dc.date.issued | 2016 | - |
dc.identifier.uri | https://scholarhub.balamand.edu.lb/handle/uob/2252 | - |
dc.description.abstract | The two 16-manganese-containing, Keggin-based 36-tungsto-4-silicates [Mn(III)10Mn(II)6O6(OH)6(PO4)4(A-α-SiW9O34)4](28-) (1) and [Mn(III)4Mn(II)12(OH)12(PO4)4(A-α-SiW9O34)4](28-) (2) have been prepared by reaction of the trilacunary Keggin precursor [A-α-SiW9O34](10-) with either Mn(OOCCH3)3·2H2O (for 1) or MnCl2·4H2O (for 2), in aqueous phosphate solution at pH 9. Polyanions 1 and 2 comprise mixed-valent, cationic {Mn(III)10Mn(II)6O6(OH)6}(24+) and {Mn(III)4Mn(II)12(OH)12}(24+) cores, respectively, encapsulated by four phosphate groups and four {SiW9} units in a tetrahedral fashion. Both polyanions were structurally and compositionally characterized by single-crystal XRD, IR, thermogravimetric analysis, and X-ray absorption spectroscopy. Furthermore, studies were performed probing the magnetic, electrochemical, oxidation catalytic, and Li-ion battery performance of 1 and 2. | en_US |
dc.language.iso | eng | en_US |
dc.title | Mixed-valent Mn16-containing heteropolyanions: Tuning of Oxidation State and Associated Physicochemical Properties | en_US |
dc.type | Journal Article | en_US |
dc.identifier.doi | 10.1021/acs.inorgchem.5b02503 | - |
dc.contributor.affiliation | Department of Chemistry | en_US |
dc.description.volume | 55 | en_US |
dc.description.issue | 6 | en_US |
dc.description.startpage | 2755 | en_US |
dc.description.endpage | 2764 | en_US |
dc.date.catalogued | 2017-11-17 | - |
dc.description.status | Published | en_US |
dc.identifier.OlibID | 175048 | - |
dc.relation.ispartoftext | Journal of inorganic chemistry | en_US |
dc.provenance.recordsource | Olib | en_US |
Appears in Collections: | Department of Chemistry |
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