Please use this identifier to cite or link to this item:
https://scholarhub.balamand.edu.lb/handle/uob/2077
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Allouch, Ahmad | en_US |
dc.contributor.author | Hassan, Inas EL | en_US |
dc.contributor.author | Zeine, Abdel Razzak El | en_US |
dc.contributor.author | Abou Dalle, Adib | en_US |
dc.contributor.author | Bouchkara, Mohammad | en_US |
dc.contributor.author | Nakat, Hanna El | en_US |
dc.contributor.author | Omar, Fawaz El | en_US |
dc.date.accessioned | 2020-12-23T09:05:52Z | - |
dc.date.available | 2020-12-23T09:05:52Z | - |
dc.date.issued | 2012 | - |
dc.identifier.uri | https://scholarhub.balamand.edu.lb/handle/uob/2077 | - |
dc.description.abstract | The separation of racemic-N-[(2Z)-4-methyl-3-(2-methylphenyl)-1,3-thiazol-2(3H)-ylidene]-N- (2-chloro-4-nitrophenyl)amine, which belongs to the 2-aryl-imino-N-(2-aryl)-thiazoline family, to collect its atropisomers, was studied using reversed-phase high-performance liquid chromatography (RP-HPLC) with hydroxypropyl-gamma-cyclodextrin (HP-γ-CD) as a complexing additive to the racemic mixture (to obtain chiral molecules) and hexane-propan-2-ol as a mobile phase. The effects of mobile phase composition, concentration of HP-γ-CD and time of incubation of the CD-substrate on separation were systematically investigated to establish the optimum resolution conditions. | en_US |
dc.format.extent | 8 p. | en_US |
dc.language.iso | eng | en_US |
dc.subject | 2-aryl-imino-N-(2-aryl)-thiazoline | en_US |
dc.subject | HP−γ-CD | en_US |
dc.subject | HPLC | en_US |
dc.subject | Atropisomeric separation | en_US |
dc.title | HPLC separaton of hydrophobic atropisomers | en_US |
dc.type | Journal Article | en_US |
dc.contributor.affiliation | Department of Chemistry | en_US |
dc.description.volume | 10 | en_US |
dc.description.issue | 2 | en_US |
dc.description.startpage | 799 | en_US |
dc.description.endpage | 807 | en_US |
dc.date.catalogued | 2019-07-04 | - |
dc.description.status | Published | en_US |
dc.identifier.OlibID | 192710 | - |
dc.relation.ispartoftext | International journal of chemical sciences | en_US |
dc.provenance.recordsource | Olib | en_US |
crisitem.author.parentorg | Faculty of Arts and Sciences | - |
Appears in Collections: | Department of Chemistry |
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