Please use this identifier to cite or link to this item: https://scholarhub.balamand.edu.lb/handle/uob/1573
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dc.contributor.authorHaidar, Ali Den_US
dc.contributor.authorBassil, Bassemen_US
dc.contributor.authorSoriano-López, Joaquínen_US
dc.contributor.authorQasim, Hafiz M.en_US
dc.date.accessioned2020-12-23T08:54:56Z-
dc.date.available2020-12-23T08:54:56Z-
dc.date.issued2019-
dc.identifier.urihttps://scholarhub.balamand.edu.lb/handle/uob/1573-
dc.description.abstractThe 9-cobalt(II)-containing trimeric, cyclic polyanion [Co9(OH)3(H2O)6(PO4)2(B-α-GeW9O34)3]21– (1) was synthesized in an aqueous phosphate solution at pH 8 and isolated as a hydrated mixed sodium–cesium salt. Polyanion 1 was structurally and compositionally characterized in the solid state by single-crystal X-ray diffraction, Fourier transform infrared spectroscopy, as well as thermogravimetric and elemental analyses. The magnetic and electrochemical properties of 1 were also studied and compared with those of its phosphorus analogue, [Co9(OH)3(H2O)6(HPO4)2(B-α-PW9O34)3]16– (Co9-P). The electrochemical water oxidation activity of the cesium salt of 1 under heterogeneous conditions was also studied and shown to be superior to that of Co9-P. The experimental results were supported by computational studies.en_US
dc.format.extent8 p.en_US
dc.language.isoengen_US
dc.title9-Cobalt(II)-Containing 27-Tungsto-3-germanate(IV) : Synthesis, Structure, Computational Modeling, and Heterogeneous Water Oxidation Catalysisen_US
dc.typeJournal Articleen_US
dc.identifier.doi10.1021/acs.inorgchem.9b01495-
dc.contributor.affiliationDepartment of Chemistryen_US
dc.description.volume58en_US
dc.description.issue17en_US
dc.description.startpage11308en_US
dc.description.endpage11316en_US
dc.date.catalogued2020-02-18-
dc.description.statusPublisheden_US
dc.identifier.ezproxyURLhttp://ezsecureaccess.balamand.edu.lb/login?url=https://doi.org/10.1021/acs.inorgchem.9b01495en_US
dc.identifier.OlibID252417-
dc.relation.ispartoftextJournal of inorganic chemistryen_US
dc.provenance.recordsourceOliben_US
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